Two Schiff bases (H2L), derived from o-vanillin and nicotinic hydrazide, and its complexes with some lanthanides (Y, Ce, Yb, Pr, Gd and Tb) have been synthesized. These compounds have been characterized by means of elemental analysis, UV–Vis spectroscopy, FTIR spectroscopy, 1H and 13C NMR (for H2L), molar conductance and room temperature magnetic measurements. The compounds are found isostructural and are formulated as {[(Z)(η2-OOCH3)Ln](-L)2[Ln(η2-OOCH3)(Z)]} (Z = H2O for Ln = Y, Ce, Pr, Gd or Tb and Z = OS(CH3)2 for Ln =Yb). The two ligand molecules act in their dideprotonated forms through one azomethine nitrogen atom, one phenoxo oxygen atom and one iminolate oxygen atom. The two Ln (III) ions are bridged by two phenoxo oxygen atoms, forming a dinuclear complex. Single crystal X-ray analysis of the ytterbium complex has revealed the nature of the structure {[(OS(CH3)2)(η2-OOCH3)Yb](-L)2[Yb(η2-OOCH3)(OS(CH3)2)]} (3). The complex crystallizes in the monoclinic space group C2/c with cell parameters of a = 13.0391(6) Å, b = 15.1199(6) Å, c = 20.7239(7) Å, β = 105.671(2)°, V = 3933.8(3) Å3, Z = 4, R1 = 0.025, wR2 = 0.65. The ytterbium atoms are eight-coordinated, and their coordination polyhedron are best described as a square antiprismatic geometry. The aromatic rings of the ligand molecule are twisted with dihedral angle of 29.23 (1)° between their mean planes.
| Published in | Science Journal of Chemistry (Volume 11, Issue 2) |
| DOI | 10.11648/j.sjc.20231102.13 |
| Page(s) | 56-63 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2023. Published by Science Publishing Group |
Hydrazide, Lanthanide, FTIR, NMR, Crystal, X-ray Diffraction
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APA Style
Fatou Barr, Papa Samba Camara, Amadou Guèye, Sofia Zazouli, Nathalie Gruber, et al. (2023). Spectroscopic Studies and X-ray Structural of Dinuclear Lanthanide (III) Complexes Derived from N'-(2-hydroxy-3-methoxybenzylidene) Nicotinohydrazide. Science Journal of Chemistry, 11(2), 56-63. https://doi.org/10.11648/j.sjc.20231102.13
ACS Style
Fatou Barr; Papa Samba Camara; Amadou Guèye; Sofia Zazouli; Nathalie Gruber, et al. Spectroscopic Studies and X-ray Structural of Dinuclear Lanthanide (III) Complexes Derived from N'-(2-hydroxy-3-methoxybenzylidene) Nicotinohydrazide. Sci. J. Chem. 2023, 11(2), 56-63. doi: 10.11648/j.sjc.20231102.13
AMA Style
Fatou Barr, Papa Samba Camara, Amadou Guèye, Sofia Zazouli, Nathalie Gruber, et al. Spectroscopic Studies and X-ray Structural of Dinuclear Lanthanide (III) Complexes Derived from N'-(2-hydroxy-3-methoxybenzylidene) Nicotinohydrazide. Sci J Chem. 2023;11(2):56-63. doi: 10.11648/j.sjc.20231102.13
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author = {Fatou Barr and Papa Samba Camara and Amadou Guèye and Sofia Zazouli and Nathalie Gruber and Farba Bouyagui Tamboura and Moussa Dieng and Mohamed Gaye},
title = {Spectroscopic Studies and X-ray Structural of Dinuclear Lanthanide (III) Complexes Derived from N'-(2-hydroxy-3-methoxybenzylidene) Nicotinohydrazide},
journal = {Science Journal of Chemistry},
volume = {11},
number = {2},
pages = {56-63},
doi = {10.11648/j.sjc.20231102.13},
url = {https://doi.org/10.11648/j.sjc.20231102.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20231102.13},
abstract = {Two Schiff bases (H2L), derived from o-vanillin and nicotinic hydrazide, and its complexes with some lanthanides (Y, Ce, Yb, Pr, Gd and Tb) have been synthesized. These compounds have been characterized by means of elemental analysis, UV–Vis spectroscopy, FTIR spectroscopy, 1H and 13C NMR (for H2L), molar conductance and room temperature magnetic measurements. The compounds are found isostructural and are formulated as {[(Z)(η2-OOCH3)Ln](-L)2[Ln(η2-OOCH3)(Z)]} (Z = H2O for Ln = Y, Ce, Pr, Gd or Tb and Z = OS(CH3)2 for Ln =Yb). The two ligand molecules act in their dideprotonated forms through one azomethine nitrogen atom, one phenoxo oxygen atom and one iminolate oxygen atom. The two Ln (III) ions are bridged by two phenoxo oxygen atoms, forming a dinuclear complex. Single crystal X-ray analysis of the ytterbium complex has revealed the nature of the structure {[(OS(CH3)2)(η2-OOCH3)Yb](-L)2[Yb(η2-OOCH3)(OS(CH3)2)]} (3). The complex crystallizes in the monoclinic space group C2/c with cell parameters of a = 13.0391(6) Å, b = 15.1199(6) Å, c = 20.7239(7) Å, β = 105.671(2)°, V = 3933.8(3) Å3, Z = 4, R1 = 0.025, wR2 = 0.65. The ytterbium atoms are eight-coordinated, and their coordination polyhedron are best described as a square antiprismatic geometry. The aromatic rings of the ligand molecule are twisted with dihedral angle of 29.23 (1)° between their mean planes.},
year = {2023}
}
TY - JOUR
T1 - Spectroscopic Studies and X-ray Structural of Dinuclear Lanthanide (III) Complexes Derived from N'-(2-hydroxy-3-methoxybenzylidene) Nicotinohydrazide
AU - Fatou Barr
AU - Papa Samba Camara
AU - Amadou Guèye
AU - Sofia Zazouli
AU - Nathalie Gruber
AU - Farba Bouyagui Tamboura
AU - Moussa Dieng
AU - Mohamed Gaye
Y1 - 2023/04/27
PY - 2023
N1 - https://doi.org/10.11648/j.sjc.20231102.13
DO - 10.11648/j.sjc.20231102.13
T2 - Science Journal of Chemistry
JF - Science Journal of Chemistry
JO - Science Journal of Chemistry
SP - 56
EP - 63
PB - Science Publishing Group
SN - 2330-099X
UR - https://doi.org/10.11648/j.sjc.20231102.13
AB - Two Schiff bases (H2L), derived from o-vanillin and nicotinic hydrazide, and its complexes with some lanthanides (Y, Ce, Yb, Pr, Gd and Tb) have been synthesized. These compounds have been characterized by means of elemental analysis, UV–Vis spectroscopy, FTIR spectroscopy, 1H and 13C NMR (for H2L), molar conductance and room temperature magnetic measurements. The compounds are found isostructural and are formulated as {[(Z)(η2-OOCH3)Ln](-L)2[Ln(η2-OOCH3)(Z)]} (Z = H2O for Ln = Y, Ce, Pr, Gd or Tb and Z = OS(CH3)2 for Ln =Yb). The two ligand molecules act in their dideprotonated forms through one azomethine nitrogen atom, one phenoxo oxygen atom and one iminolate oxygen atom. The two Ln (III) ions are bridged by two phenoxo oxygen atoms, forming a dinuclear complex. Single crystal X-ray analysis of the ytterbium complex has revealed the nature of the structure {[(OS(CH3)2)(η2-OOCH3)Yb](-L)2[Yb(η2-OOCH3)(OS(CH3)2)]} (3). The complex crystallizes in the monoclinic space group C2/c with cell parameters of a = 13.0391(6) Å, b = 15.1199(6) Å, c = 20.7239(7) Å, β = 105.671(2)°, V = 3933.8(3) Å3, Z = 4, R1 = 0.025, wR2 = 0.65. The ytterbium atoms are eight-coordinated, and their coordination polyhedron are best described as a square antiprismatic geometry. The aromatic rings of the ligand molecule are twisted with dihedral angle of 29.23 (1)° between their mean planes.
VL - 11
IS - 2
ER -
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